Sami Publishing Company (SPC) Asian Journal of Nanosciences and Materials 2645-775X 2588-669X 2 1 2019 01 01 Polymer-based Material for Lithium-Ion Batteries: Structure, Material Engineering, Device Performance and Challenges (Review) 1 26 EN Salami Mutiah Department of Chemistry, University of Ilorin, Ilorin, Kwara State, Nigeria salamimutiah@gmail.com Hitler Louis 0000-0002-0286-2865 Department of Pure and Applied Chemistry, Faculty of Physical Sciences, University of Calabar, Calabar, Cross River State, Nigeria. | CAS Key Laboratory for Nanosystem and Hierarchical Fabrication, CAS Centre for Excellence in Nanoscience, National Centre for Nanoscience and Technology, University of Chinese Academy of Sciences,Beijing, China. louis@nanoctr.cn Amusan Oluwatobi Omotola Department of Chemistry, University of Ilorin, Ilorin, Kwara State, Nigeria. aoomotola@gmail.com Saud Uz Zafar 0000-0001-8708-3272 CAS Key Laboratory for Nanosystem and Hierarchical Fabrication, CAS Centre for Excellence in Nanoscience, National Centre for Nanoscience and Technology, University of Chinese Academy of Sciences, Beijing, China saud@nanoctr.cn Thomas O. Magu Department of Pure and Applied Chemistry, Faculty of Physical Sciences, University of Calabar, Calabar, Cross River State, Nigeria. Adejoke T. Hamzat Department of Chemistry, University of Ilorin, Ilorin, Kwara State, Nigeria. Amos I. Pigweh CAS Key Laboratory for Nanosystem and Hierarchical Fabrication, CAS Centre for Excellence in Nanoscience, National Centre for Nanoscience and Technology, University of Chinese Academy of Sciences, Beijing, China. Ozioma U. Akakuru Department of Pure and Applied Chemistry, Faculty of Physical Sciences, University of Calabar, Calabar, Cross River State, Nigeria. | Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Zhejiang, China. Aderemi T Adeleye Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, P.R. China. Benedict Iserom Ita Department of Pure and Applied Chemistry, Faculty of Physical Sciences, University of Calabar, Calabar, Cross River State, Nigeria. 10.26655/ajnanomat.2019.1.1 Batteries are a major technological challenge in this new century as they are a key method to make use of energy efficiently. Nowadays Lithium-ion batteries (LIBs) appeared to be one of the most important energy storage technologies. Today’s Li-ion technology has conquered the portable electronic markets and still on the track of fast development. The success of lithium-ion technology will depend largely on the cost, safety, cycle life, energy, and power, which are in turn determined by the component materials used for its fabrication. Accordingly, this review focuses on the challenges of organic based materials and prospects associated with the electrode materials. Specifically, the issues associated with organic based batteries, advances and prospects are presented. This review aims to summarize the fundamentals of the polymer-based material for lithium-ion batteries (LIBs) and specifically highlight its recent major advancement in material design, challenges, performance and finally its prospects. We anticipate that this Review will inspire further improvement in organic electrolyte materials and the electrode for the battery as energy device storages. Some of these concepts, relying on new ways to prepare electrode materials by the use of eco-efficient processes, on the use of organic rather than inorganic materials in order to overcome environmental issues associated with their use. Organic electrodes are important for solid electrode batteries because they can make device cost-effective, allow flexibility, and can also enable the use of multivalent ions without the problems typically associated with inorganic compounds. Polymer,Lithium,ion,Battery,performance https://www.ajnanomat.com/article_75266.html https://www.ajnanomat.com/article_75266_bcb34341e933a6a6de21517e6f794b7c.pdf

Sami Publishing Company (SPC) Asian Journal of Nanosciences and Materials 2645-775X 2588-669X 2 1 2019 01 01 Facile Preparation of Novel Zinc Oxide Nano Sheets and Study of Its Optical Properties 27 36 EN Parvin Gharbani Department of Chemical Engineering, Ahar Branch, Islamic Azad University, Ahar, Iran parvingharbani@yahoo.com Amir Mehalizadeh Department of Chemical Engineering, Ahar Branch, Islamic Azad University, Ahar, Iran amir.m.tnt@gmail.com 10.26655/ajnanomat.2019.1.2 The zinc oxide nano sheets were prepared by zinc sulfate and sodium hydroxide via precipitated method and, then, calcinated at 300 oC. In order to have a reliable characterization of the synthesized ZnO nanosheets, FTIR, XRD, FESEM, XRF, TGA and Raman techniques were applied. The phase and purity of zinc oxide nanosheets were confirmed by XRD and XRF, respectively. FESEM results showed the morphology of zinc oxide and revealed that the size of the prepared powder is in the range of nanometer. TGA analysis revealed that there are two endothermic reactions which have occurred at 35-200oC and 300 - 400oC temperatures. Optical spectra indicated that the band gap of the prepared nanosheets transmitted a red shift. Zinc oxide,Synthesis,Optical properties,Nano Sheet https://www.ajnanomat.com/article_75244.html https://www.ajnanomat.com/article_75244_64471746e1887d547d94463473ee8b17.pdf

Sami Publishing Company (SPC) Asian Journal of Nanosciences and Materials 2645-775X 2588-669X 2 1 2019 01 01 Embedded Ag NPs in Cysteine-Poly (acrylic acid) Hydrogel with Antibacterial Activity 37 48 EN Soghra Fathalipour Department of Chemistry, Payame Noor University, PO Box 19395-3697 Tehran, Iran. s.fathalipour@pnu.ac.ir Mahdiye Ghanbarizadeh Department of Chemistry, Payame Noor University, PO Box 19395-3697 Tehran, Iran. ghanbarizadeh@ymail.com 10.26655/ajnanomat.2019.1.3 In this research,Ag NPs were loaded on cysteine modified poly(acrylic acid) (PAA) hydrogel. Obtainedcysteine-hydrogel (Chydrogel) having different functional groups could stabilize Ag NPs better than un-modified hydrogel due to the presence of disulfid bondings. First, obtained PAA hydrogel from radical polymerization was conjugated with cysteine-hydrochloride (Cys) through amidation reaction and then was used as a substrate and stabilization reagent for Ag ions. Ag ions were reduced on Chydrogel in the presence ofNaBH4 as reducing reagent. The resultant nanocomposite was well characterized by using UV–vis, FT-IR, XRD and SEM techniques. Furthermore, the resultant Ag NPs on the surface of Chydrogel showedhigh antibacterial behavior against Gram-negative E. coliand Gram-positive S. aureusdue to the high reaction of thiol-functions with the outer cell surface. hydrogels,Composites,antibacterial,inorganic materials,Ag NPs https://www.ajnanomat.com/article_73762.html https://www.ajnanomat.com/article_73762_575158cc3cf3fcd85ba3df0bc973b90a.pdf

Sami Publishing Company (SPC) Asian Journal of Nanosciences and Materials 2645-775X 2588-669X 2 1 2019 01 01 Host-guest interaction in chitosan– MX (3-chloro-4-(dichloromethyl)-5-hydroxy-2(5H)-furanone) complexes in water solution: Density Functional Study 49 65 EN Fatemeh Houshmand Computational Physical Sciences Research Laboratory, School of Nano-Science, Institute for Research in Fundamental Sciences (IPM), P.O. Box 19395-5531 Tehran, Iran. | Department of Laboratory, Water and Wastewater quality control office, TPWW.Co. Tehran, Iran. houshmandf1@gmail.com Hamide Neckoudaria Department of Laboratory, Water and Wastewater quality control office, TPWW.Co. Tehran, Iran. Majid Baghdadi Department of Environmental Engineering, Graduate Faculty of Environment, University of Tehran, Tehran, Iran m.baghdadi@ut.ir 10.26655/ajnanomat.2019.1.4 The present study is an attempt to provide an insight into the stability, in terms of interaction energy and thermodynamic parameter, and reactivity, quantified by reactivity descriptors, of the chitosan-MX and its analogous (EMX and ZMX) system. In this system a component is, MX (3-chloro-4-(dichloromethyl)-5-hydroxy-2(5H)-furanone) a mutagenic halogenated disinfection by products which present in drinking water. And, chitosan is an eco-friendly nano-adsorbent to remove oils, grease, heavy metals and the fine particulate matter from water solution. Electronic and structural properties of chitosan during functionalization by metal were studied by density functional theory (DFT) calculations. Isolated and functionalized chitosan were optimized and their properties were evaluated. The results indicated that the properties of linking sites detect the most significant effects of functionalization process.<br /> Degradation efficiency of MX and its analogous in water solvent and also the possibility of absorption of MX by chitosan nanoparticles in aqueous solution were studied via different level of theory. Halogenated furanone (MX),MX analogous,Disinfection Byproducts,Chitosan,Density functional theory https://www.ajnanomat.com/article_75234.html https://www.ajnanomat.com/article_75234_f855570545c3164d7d44107a9f55621d.pdf

Sami Publishing Company (SPC) Asian Journal of Nanosciences and Materials 2645-775X 2588-669X 2 1 2019 01 01 Curcumin-hybrid Nanoparticles in Drug Delivery System (Review) 66 91 EN Somayeh Deljoo Department of plant sciences, Faculty of natural sciences, University of Tabriz, Tabriz, Iran somayeh.deljoo@gmail.com Navid Rabiee Department of Chemistry, Shahid Beheshti University, Tehran, Iran nrabiee94@gmail.com Mohammad Rabiee 1. Biomaterials Group, Faculty of Biomedical Engineering, Amirkabir University of Technology, Tehran, Iran mrabiee@aut.ac.ir 10.26655/ajnanomat.2019.1.5 Extensive studies on curcumin has improved that it has certain therapeutic role for different kinds of diseases such as cancer. Regardless of its positive features, its application is hampered by its low water solubility, bioavailability, and low cellular uptake. During last year’s several ways have been developed to protect curcumin from degradation and increase its capability to targeting unhealthy cells. The progress in nanotechnology encouraged nanotechnologists to formulate nanoparticles encapsulating curcumin, such as polymer nanoparticles, solid nanoparticles, liposome/lipid nanoparticles, micelles, dendrimers, polymer conjugates, etc. to enhance sustained release of curcumin at target cells and to improve curcumin bioavailability. Nowadays newer formulations of nanoparticles as called Hybrid nanoparticles are designed in order to efficient and specific targeting of curcumin that result in improved therapeutic efficacy of curcumin with high biocompatibility with the aid of aptamers, folic acid, chitosan coated halloysite loaded with curcumin-Au hybrid nanoparticle and so on. This review describes a number of hybrid nanoparticles formulated and their efficacy in specific targeting to cancerous cells. curcumin,hybrid nanoparticles,Drug delivery system https://www.ajnanomat.com/article_79350.html https://www.ajnanomat.com/article_79350_ab1397dcb9ea1dfb47f4db92ec6bbbc8.pdf

Sami Publishing Company (SPC) Asian Journal of Nanosciences and Materials 2645-775X 2588-669X 2 1 2019 01 01 Preparation and characterisation of SnO–Fe2O3 nanocomposites 92 98 EN Alagappan Subramaniyan Department of Physics,Thiagarajar College of Engineering,Madurai 625015,India alsphy@tce.edu Veeraiah Veeraganesh Department of Physics,Thiagarajar College of Engineering,Madurai 625015,India vvgphy@tce.edu 10.26655/ajnanomat.2019.1.6 Nanocomposites are novel materials which are yet to be explored and utilised to its complete potential. Nanocomposites can be tailored by the volume fraction of the matrix, fibre and also by the size and shape of the nanophase material in the composite. Preparing nanocomposite with a desired shape and size remains a challenge. In the present work nanocomposites of SnO–Fe2O3.are prepared by a sol gel route with Ferric chloride and Tin chloride as precursors. The prepared nanocomposites are characterised by X-ray Diffraction(XRD), Ultraviolet Visible Spectroscopy (UV),Scanning Electron microscopy(SEM) and Fourier Transform Infrared Spectroscopy(FTIR). The crystallite size obtained is approximately 60 nm, with a band gap of 3.55 eV. The band gap of the composite could further be tuned with nanosize. Nanocomposite,SnO–Fe2O3,Sol gel,XRD,UV and FTIR https://www.ajnanomat.com/article_79380.html https://www.ajnanomat.com/article_79380_9f807478cb8d1e8e07f967f56188eb13.pdf

Sami Publishing Company (SPC) Asian Journal of Nanosciences and Materials 2645-775X 2588-669X 2 1 2019 01 01 Vitex negundo leaf extract mediated synthesis of ZnO nanoplates and its antibacterial and photocatalytic activities 99 110 EN M Anbuvannan Department of Physics, Sri Akilandeswari Women’s College, Wandiwash-604408, Tamil Nadu, India. anbuphy85@gmail.com M Ramesh Department of Physics, M.V. Muthiah Government Arts College for Women, Dindigul- 624 001,Tamil Nadu, India. rameshm82phy@gmail.com E Manikandan Department of Physics ,Thiruvalluvar University College of Arts & Science, Thennangur-604408, Tamil Nadu, India. maniphysics@gmail.com R Srinivasan Tamil Nadu State Council for Science and Technology (TNSCST), DOTE Campus, Chennai-600 025, Tamil Nadu, India. ms.tanscst@nic.in 10.26655/ajnanomat.2019.1.7 Nanocrystals of ZnO have been prepared using vitex negundo leaf extract via a simple green method. The confirmation of ZnO formation was carried out by UV–Vis-diffuse reflectance spectroscopy (UV-Vis DRS). The prepared nanocrystals were further characterized by photoluminescence (PL), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), Field emission-scanning electron microscopy (FE-SEM) and Transmission electron microscopy (TEM). FE-SEM shows the ZnO nanoparticles are nanoplates like structure. With the aim of assessing the photocatalytic activities of ZnO nanocrystals the degradation of methylene blue (MB) under UV radiation was analyzed. Further, the antibacterial activities of synthesized ZnO nanoparticles were screened against S. aureus, S. paratyphi, V. cholerae, and E. coli. Zinc oxide,Vitex negundo,nanoplate,Photocatalytic,Antibacterial Activity https://www.ajnanomat.com/article_79938.html https://www.ajnanomat.com/article_79938_1b4afa9478e38df3d7fbd568c299c701.pdf

Sami Publishing Company (SPC) Asian Journal of Nanosciences and Materials 2645-775X 2588-669X 2 1 2019 01 01 Synthesis And Characterization of Al Doped And (Co, Al) co-doped ZnO Nanoparticles via Chemical co-precipitation Method 111 119 EN S Venkatramana Reddy Department of Physics, Sri Venkateswara University, Tirupati-517 502, A.P., India. drsvreddy123@gmail.com Swapna Peyyala Department of Physics, Sri Venkateswara University, Tirupati-517 502, A.P., India. swapna.pyl@gmail.com 10.26655/ajnanomat.2019.1.8 Pure, Al doped and (Co, Al) co-doped ZnO nanopowders have been synthesized through chemical co precipitation method at Room temperature, using poly ethylene glycol (PEG) as stabilizing agent. The synthesized samples are characterized by X-ray Diffraction (XRD), Scanning electron microscopy (SEM) & Energy-Dispersive X-ray spectroscopy (EDS), Transmission electron microscopy (TEM), High resolution TEM, SAED and Vibrating sample magnetometer (VSM). XRD results reveals that all the samples possess hexagonal wurtzite crystal structure with no secondary phases. SEM analysis demonstrated the morphology of the Pure, Al doped and (Co, Al) co-doped ZnO nanoparticles while EDS spectrum shows the incorporation of dopant elements. TEM illustrations reveal the exact size of the crystallites, which is approximately confirmed by the XRD data. HRTEM images of the Pure and Al doped ZnO nanoparticles shows clear lattice fringes about 5 nm and co-doped images reveal lattice fringes are about 2 nm. In determining the magnetic properties, VSM technique has been used and VSM analysis of (Co, Al) co-doped samples reveal Super paramagnetic or weak ferro magnetic nature at Room temperature. HRTEM,RTFM,Lattice fringes,Magnetic properties,VSM https://www.ajnanomat.com/article_79949.html https://www.ajnanomat.com/article_79949_1af67767a9d779bde6d70fa275d3dc54.pdf